Advances in Organic Synthesis

Volume 4

by

Atta-ur-Rahman

DOI: 10.2174/97816080547561130401
eISBN: 978-1-60805-475-6, 2013
ISBN: 978-1-60805-602-6
ISSN: 1574-0870 (Print)
ISSN: 2212-408X (Online)



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Advances in Organic Synthesis is a book series devoted to the latest advances in synthetic approaches towards challen...[view complete introduction]

Table of Contents

Preface

- Pp. i- (1)

Atta-ur-Rahman

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List of Contributors

- Pp. ii-iv (3)

Atta-ur-Rahman

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Asymmetric Synthesis of α-Unsubstituted β-Hydroxy Acids

- Pp. 3-35 (33)

Jan Spengler and Fernando Albericio

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Rhodium-Catalyzed Hydroformylation Promoted by Modified Cyclodextrins: Current Scope and Future Developments

- Pp. 36-63 (28)

Frédéric Hapiot, Loïc Leclercq, Nathalie Azaroual, Sophie Fourmentin, Sébastien Tilloy and Eric Monflier

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Application of Bismuth(III) Reagents and Catalysts to the Synthesis of Heterocyclic Compounds of Pharmaceutical Interest

- Pp. 64-181 (118)

Jorge A. R. Salvador, Rui M. A. Pinto and Samuel M. Silvestre

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Applications of Dioxomolybdenum(VI) Complexes to Organic Synthesis

- Pp. 182-266 (85)

Roberto Sanz and María R. Pedrosa

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Reactions of Nitrogen Derivatives of Carbonyl Compounds with Phenyliodoso Diacetate in Organic Synthesis

- Pp. 267-316 (50)

Antigoni Kotali, Elvira Kotali, Ioannis S. Lafazanis and Philip A. Harris

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Streamlining Organic Free Radical Synthesis through Modern Molecular Technology: from Polymer Supported Synthesis to Microreactors and Molecular Reactors

- Pp. 317-344 (28)

V. Tamara Perchyonok

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Emerging Role of Room Temperature Ionic Liquids (RTILs) in Carbohydrate Chemistry

- Pp. 345-408 (64)

Virendra Prasad, Divya Kushwaha, Kunj B. Mishra, Lallan Mishra and Vinod K. Tiwari

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Synthesis of Trifluoromethyl-Substituted Fused Bicyclic Heterocycles and their Corresponding Benzo-Fused Analogues

- Pp. 409-455 (47)

Ahmed H. M. Elwahy and Mohamed R. Shaaban

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Index

- Pp. 456-478 (23)

Atta-ur-Rahman

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Preface

The present volume presents some recent exciting advances in synthetic organic chemistry.

In the first article, Spengler and Albericio review various possible routes to the asymmetric synthesis of α-unsubstituted β-hydroxy acids. In another interesting contribution, Hapiot and his team describe the role of modified cyclodextrins in rhodium-catalyzed hydroformylation. Salvador and co-workers focus on applications of bismuth (III) reagents and catalysts in the synthesis of hetrocyclic compounds of pharmaceutical interest. Next, Sanz and Pedrosa review applications of dioxomolybdenum(VI) complexes in organic synthesis. Kotali et al. discuss the progress in the reactions of nitrogen derivatives of carbonyl compounds with phenyliodoso diacetate. Perchyonok present a detailed review on improvements in free radical producing technology. Tiwari and colleagues highlight the rapid increase in novel applications of ionic liquids in carbohydrate chemistry. In the last chapter, Shaaban and Elwahy review the synthesis of trifluoromethyl-substituted fused bicyclic heterocycles and their corresponding benzo-fused analogues.

I hope that this volume will prove to be of considerable interest to all those practicing art of organic synthesis.

This eBook would not have been possible without the cooperation of all the contributing authors. I am grateful for the time and efforts made by the editorial personnel, especially Mr. Mahmood Alam (Director Publications), Taimur A. Khan and Sarah A. Khan at Bentham Science Publishers.

Atta-ur-Rahman, FRS
Kings College
University of Cambridge
Cambridge
UK

List of Contributors

Editor(s):
Atta-ur-Rahman
University of Cambridge
UK




Contributor(s):
Jan Spengler
Institute for Research in Biomedicine
Barcelona Science Park
University of Barcelona
Baldiri Reixac 10
Barcelona, E-08028
Spain


Fernando Albericio
Department of Organic Chemistry
University of Barcelona
Martí i Franqués 1-11
Barcelona, E-08028
Spain


Frédéric Hapiot
Université d’Artois
Unité de Catalyse et de Chimie du Solide
UMR CNRS 8181
Rue Jean Souvraz SP 18
Lens, Cédex 62307
France


Loïc Leclercq
Université d’Artois
Unité de Catalyse et de Chimie du Solide
UMR CNRS 8181
Rue Jean Souvraz SP 18
Lens, Cédex 62307
France


Nathalie Azaroual
Université de Lille 2
Faculté de Pharmacie, LCOM
Equipe "RMN et Photochimie"
UMR CNRS 8009, BP 83
Lille, 59006



Sophie Fourmentin
Université du Littoral
Laboratoire de Synthèse Organique et Environnement
EA 2599, 145 Avenue Maurice Schumann
Dunkerque, 59140
France


Sébastien Tilloy
Université d’Artois
Unité de Catalyse et de Chimie du Solide
UMR CNRS 8181
Rue Jean Souvraz SP 18
Lens, Cédex 62307
France


Eric Monflier
Université d’Artois
Unité de Catalyse et de Chimie du Solide
UMR CNRS 8181
Rue Jean Souvraz SP 18
Lens, Cédex 62307
France


Jorge A. R. Salvador
Laboratório de Química Farmacêutica
Faculdade de Farmácia da Universidade de Coimbra
Pólo das Ciências da Saúde
Azinhaga de Santa Comba
Coimbra, 3000-548
Portugal


Rui M. A. Pinto
Department of Veterinary Medicine
Escola Universitária Vasco da Gama
Mosteiro S. Jorge de Milréu
Estrada da Conraria
Castelo Viegas, Coimbra, 3040-714
Portugal


Samuel M. Silvestre
Health Sciences Research Centre
Faculdade de Ciências da Saúde
Universidade da Beira Interior
Av. Infante D. Henrique
Covilhã, 6201-506
Portugal


Roberto Sanz
Departamento de Química
Facultad de Ciencias
Universidad de Burgos
Pza. Misael Bañuelos s/n
Burgos, 09001
Spain


María R. Pedrosa
Departamento de Química
Facultad de Ciencias
Universidad de Burgos
Pza. Misael Bañuelos s/n
Burgos, 09001
Spain


Antigoni Kotali
Laboratory of Organic Chemistry
College of Engineering
University of Thessaloniki
Thessaloniki, GR-54124
Greece


Elvira Kotali
Laboratory of Organic Chemistry
College of Engineering
University of Thessaloniki
Thessaloniki, GR-54124
Greece


Ioannis S. Lafazanis
Laboratory of Organic Chemistry
College of Engineering
University of Thessaloniki
Thessaloniki, GR-54124
Greece


Philip A. Harris
GlaxoSmithKline
1250 South Collegeville Road
P.O.Box 5089
Collegeville
PA, 19426-0989
USA


V. Tamara Perchyonok
VTPCHEM PTY LTD
Melbourne, 3163
Australia


Virendra Prasad
Central Institute for Research on Cotton Technology
Adenwala Road, Matunga
Mumbai, 4400019
India


Divya Kushwaha
Department of Chemistry
Centre of Advanced Study
Banaras Hindu University
Varanasi, 221005
India


Kunj B. Mishra
Department of Chemistry
Centre of Advanced Study
Banaras Hindu University
Varanasi, 221005
India


Lallan Mishra
Department of Chemistry
Centre of Advanced Study
Banaras Hindu University
Varanasi, 221005
India


Vinod K. Tiwari
Department of Chemistry
Centre of Advanced Study
Banaras Hindu University
Varanasi, 221005
India


Ahmed H. M. Elwahy
Department of Chemistry
Faculty of Applied Science
Umm Al-Qura University
Makkah Almukkarramah
Saudi Arabia


Mohamed R. Shaaban
Department of Chemistry
Faculty of Science
Cairo University
Giza
Egypt




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